 | Forum
Thread | A match thread anyone? Stockton v Rochdale FA trophy
by Yorkshire_Dale at 16:00 8 Jan 2025
Just seen on X that the Referee has confirmed the GAME IS ON! yippee, at last some action.
Did n't know it was in any doubt. Really Good Luck to the Team and especially any of our travelling fans, stay sober apparently it's icy underfoot.
Let's get cracking and attacking. |
| News
Comment | TVOS Preview - Rochdale v Solihull Moors
by Sikhapk at 11:57:45
ISO 28000 certification in Hyderabad ensures that organizations have a robust security management system for their supply chains. It focuses on risk assessment, security controls, and the prevention of potential disruptions. This certification is particularly relevant for industries involved in logistics, manufacturing, and distribution. Achieving ISO 28000 helps businesses enhance their resilience and build trust with clients and stakeholders.
https://www.b2bcert.com/iso-28000-certification-in-hyderabad/
|
| Forum
Thread | What do you know flash games?
by Pixelik19 at 09:43 8 Jan 2025
Even while flash games lack realistic visuals, their simplicity and vibrancy are what make them so appealing. Players were immediately drawn in by the visually appealing and captivating games' vibrant animations and creative artwork https://flash-games.io/ |
| Forum
Thread | EA FC 25 TOTY Event Hot Returns!
by Liiyan at 06:27 8 Jan 2025
EA FC 25 TOTY, the most popular annual event among FC 25 players is returning. As in previous events, players can choose the players they think will perform the best and have the most influence in 2024, and vote for them to improve their statistics and ratings in the game.
This EA FC 25 TOTY will run from January 6, 2025 to January 12, 2025. Players can go to the EA FC 25 TOTY official website to make their choices. After entering the website page, we will see the candidates for each position of the men's and women's teams respectively. Players need to fill in the position of the person who meets your heart in the starting lineup. When you are satisfied, you can click the vote button. Be careful not to forget to vote for the 12th player, which usually happens at the end of the event.
I believe everyone has their own opinions on the candidates for the best player of the year. After the event is over, players need to pay attention to their social media to see the winners. This year's 24 winners will still be added to the game as game items. This time the player card is in gold and blue as the main color, which is very worth looking forward to.
These items are expected to be gradually added to the game in the form of FC 25 Packs after January 17th. Players are recommended to visit IGGM.com to purchase and get these packs at a preferential price. Lucky players will have the opportunity to get their favorite TOTY players and add them to their team, or they can also sell other players drawn to make high profits. After all, TOTY player cards must be very rare and precious assets in FC 25.
According to past traditions, these player cards will be released at different times according to player positions, and the team will be released only after all the players are released. Therefore, FC 25 players may have to keep an eye on social media for the latest news, or check the latest player items and the latest promotions on IGGM.com, which is a very convenient way.
The above is the main information of the FC 25 TOTY event, I hope it can help you.
|
| Forum
Thread | Another Tuesday night rearrangement?
by EllDale at 22:12 7 Jan 2025
Woking have won tonight in the FA Trophy so will be playing in the next round on Saturday 1st February when we should have gone there irrespective of whether or not we win on Wednesday or not. |
 | Forum
Thread | Two departures
by Duckegg at 17:13 7 Jan 2025
Penny came to the club on non contract terms and has now left the club.
Henry has gone back to Charlton after suffering a broken foot in November.... |
| Forum
Thread | Project 5000
by Dale_4_Life at 06:45 7 Jan 2025
Looks like it can be done.
Interesting article in the Sunday Times last weekend with Andy Woodman at Bromley.
One paragraph stood out and encouragement for RAFC.
"The capacity at the ground is 5000 and we sell out every home game. When i came to the football club the average gate was 900 and we had 200 season ticket holders. Now we have sell outs and 2500 season ticket holders. The owner and chairman Robin Stanton-Gleaves is building the club very intelligently. |
| Forum
Thread | Dale Young Reporters
by Dale_4_Life at 06:38 7 Jan 2025
Fantastic initiative by the club and well done the 3 players Ryan Tarryn and Kairo...
Two things jumped out to me.
1. The players seemed genuinely happy to be involved.
2. Which player would you most like to have dinner with?.. Quick as a flash they all agreed Toby.. TAR is obviously a real character and as well as a very decent footballer some much needed fun in any dressing room.
Dale have scored some own goals in the last few weeks (IMO) but this was spot on. |
| Forum
Thread | 2-bromophenol
by samir123 at 04:53 6 Jan 2025
<a href=" https://www.lifechempharma.com/product/2-bromophenol-manufacturer/"> 2-Bromophenol</a>
is an aromatic halogenated phenol compound commonly used as a building block in organic synthesis. It is an ortho-substituted bromophenol, where a bromine atom is attached to the benzene ring at the second position relative to the hydroxyl group (-OH). The presence of both hydroxyl and halogen groups makes it a versatile reagent in the synthesis of pharmaceuticals, agrochemicals, and fine chemicals.
Chemical Structure and Properties
Property Description
Chemical Name 2-Bromophenol
Molecular Formula C₆H₅BrO
Molecular Weight 173.01 g/mol
CAS Number 95-56-7
Appearance White to pale yellow crystalline solid
Boiling Point 210°C
Melting Point 7°C
Density 1.77 g/cm³
Solubility Slightly soluble in water, soluble in organic solvents like ethanol, ether, and chloroform
Chemical Structure
The structure of 2-bromophenol consists of a benzene ring with two functional groups:
Hydroxyl group (-OH) at the first position.
Bromine atom (Br) at the second position (ortho position).
This combination gives the molecule unique chemical and physical properties, including polarity, reactivity, and solubility.
Synthesis of 2-Bromophenol
2-Bromophenol can be synthesized by:
Bromination of Phenol:
Phenol undergoes electrophilic aromatic substitution with bromine in the presence of a catalyst (like FeBr₃), resulting in bromophenol. By controlling the reaction conditions, the ortho isomer (2-bromophenol) can be selectively produced.
Reaction:
C
6
H
5
OH
+
Br
2
→
C
6
H
4
BrOH
+
HBr
C
6
H
5
OH+Br
2
→C
6
H
4
BrOH+HBr
Direct Bromination with NBS (N-Bromosuccinimide):
NBS is used as a brominating agent in the presence of a radical initiator (like light or peroxide) to selectively brominate phenol derivatives at the ortho position.
Applications of 2-Bromophenol
Intermediate in Pharmaceutical Synthesis:
2-Bromophenol is a key starting material in the production of antifungal agents, analgesics, and anti-inflammatory drugs.
It is used to prepare brominated benzodiazepines and other heterocyclic compounds.
Building Block in Organic Synthesis:
It is used as a precursor for the synthesis of aryl ethers, aryl amines, and aryl halides.
The hydroxyl and bromine groups facilitate substitution and coupling reactions, such as:
Suzuki coupling
Buchwald-Hartwig amination
Ullmann reaction
Agrochemical Synthesis:
Used in the preparation of fungicides, herbicides, and pesticides.
Polymer Chemistry:
It is employed in the modification of polymers and resins, improving their chemical and thermal properties.
Dye and Pigment Manufacturing:
The compound is used in the synthesis of azo dyes and organic pigments.
Biochemical Studies:
It serves as a model compound in studying the interaction of phenolic compounds with biological systems, particularly their role in enzyme inhibition and antioxidant activity.
Reactivity of 2-Bromophenol
2-Bromophenol exhibits both nucleophilic and electrophilic reactivity due to the presence of the hydroxyl and bromine groups:
Nucleophilic Substitution (SNAr):
The bromine atom can be displaced by a nucleophile (e.g., amine, thiol, or alkoxide) to form various derivatives.
Electrophilic Substitution:
The hydroxyl group activates the benzene ring, making it more susceptible to further electrophilic substitutions, such as nitration, sulfonation, or alkylation.
Oxidation:
The hydroxyl group can be oxidized to form quinones or other oxidized phenol derivatives.
Safety and Handling
2-Bromophenol is classified as a hazardous substance and should be handled with care.
Hazards:
Causes skin and eye irritation.
Harmful if inhaled or ingested.
Can cause environmental damage if released into water bodies.
Precautions:
Wear PPE: Gloves, goggles, and a lab coat should be worn while handling.
Work in a fume hood: Avoid inhaling vapors.
Proper storage: Keep in a cool, dry place, away from heat, moisture, and incompatible substances (e.g., strong oxidizers).
First Aid Measures:
Skin contact: Wash thoroughly with soap and water.
Eye contact: Rinse with water for at least 15 minutes and seek medical attention.
Inhalation: Move to fresh air immediately and seek medical help if symptoms persist.
Environmental Impact
2-Bromophenol can be toxic to aquatic life and should not be released into the environment. Proper waste disposal methods must be followed in compliance with local regulations.
Conclusion
2-Bromophenol is a valuable reagent in organic synthesis, particularly in the pharmaceutical and agrochemical industries. Its unique structure and reactivity make it an important intermediate in various chemical transformations. While it is a useful compound, appropriate safety precautions should be taken to handle it safely due to its hazardous properties. |
 | Forum
Thread | Ratcliffe help bloods donors
by DaleBars at 09:07 5 Jan 2025
Morning, if anybody can help clear the snow from the car park for the blood donor session. Will greatly appreciate it. Only live you local. Thank you |
 | Forum
Thread | Aaron Morley
by 442Dale at 16:57 4 Jan 2025
Two consecutive 90th minute winners for two different clubs (Wycombe and Bolton) against the same team (Exeter). All in the last four days.
|
|
|
By continuing to use the site, you agree to our use of cookies and to abide by our Terms and Conditions.
